It is a product of the dehydration of sugars, as occur in a variety of agricultural byproducts, including corncobs, oat, wheat bran, and sawdust. Safety data sheet ifc, supplier in furfural and furfuryl. Subscribe to our newsletter to keep up to date on our latest flavors and fragrances offerings. Material safety data sheet ifc, supplier in furfural and. Use pattern and formulations furfural is a new pesticidal active ingredient intended for use as a fumigant to control root infesting plant parasitic nematodes and fungal plant diseases in greenhouse soil used for growing ornamentals and other nonfood commodities. It has a role as a maillard reaction product and a metabolite. Du pont abandons the furfural thfadiponitrile process. Furfural or furfuryl alcohol msds sheet of manufacturers.
Korenman and resnik 1930 and animals deichmann and gerarde 1969. In the atmosphere, furfural is expected to exist predominately in the vapor phase. Hazards identification target organs eyes, respiratory system, skin, liver, kidney, spleen potential health effects. Material safety data sheet section 1 furfural 1 chemical product and company identification msds name. Firstaid measures general advice if symptoms persist, call a physician. Several drops of furfural in standard eye tests with rabbits cause significant irrita tion but no irreversible. Furfural article about furfural by the free dictionary. Longterm exposure to furfural may cause sensitization of the skin, loss of the sense of taste, numbness of the tongue, and breathing problems. Finoric, etymologically derived from our business line of fine inorganic, organic and industrial chemicals, is the internationally preferred source for chemicals.
Purchase the chemistry and technology of furfural and its many byproducts, volume 1st edition. Destruction by the vapor phase reaction with photochemically produced hydroxyl radicals is expected to be an important process with an estimated halflife of 0. The information provided on this msds is correct to the best of our knowledge, information and belief at the date of its publication. As in any fire, wear a selfcontained breathing apparatus in pressuredemand, mshaniosh approved or equivalent, and full protective gear. Colourless to yellow oily liquid which browns on storage, pungent, sweet, breadlike, caramellic, cinnamonalmondlike flavour, odour resembles benzaldehyde food and agriculture organization. International furan chemicalsifc is supplier in furfural. Furfural is an organic compound with the formula c 4 h 3 ocho. It forms condensation products with many types of compounds.
More information on the manner in which spectra in this collection were collected can be found here. Safety data sheet according to 29cfr19101200 and ghs rev. The first scientific opinion sccnfp082204 on furfural was adopted by the sccnfp during. Furfural c 4 h 3 ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. Furfural cas 98011 gr for analysis acs find msds or sds, a coa, data sheets and more information. Find msds or sds, a coa, data sheets and more information. Furfural is extensively utilized as a solvent during the manufacture of refractory materials, resinbonded grinding wheels, and butadiene extraction due to its superior physical properties. The production of furfural via diluteacid hydrolysis of lignocellulosic materials has been under study for many years. Dec 17, 2019 furfural countable and uncountable, plural furfurals organic chemistry a heterocyclic aldehyde derivative of furan. Material safety data sheet northwest missouri state. The strong shift towards the development of biobased chemicals on account of volatile petrochemical prices and growing environmental concerns is expected to remain a key driver for the growth of global furfural market. Du pont abandons the furfuralthfadiponitrile process. View download disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Furfural derivatives are tested as automotive fuel in blends with gasoline.
Background furfural cas no 98011 and ec no 2026277 has a widespread use in cosmetic products as a perfumery ingredient. Based on directive 200158ec of the commission of the european communities. Furfural appears as colorless or reddishbrown mobile liquids with. Expansion of the market is attributed to the increase the demand for furfural from plastics industries and refineries. Furfuralwater vaporliquid equilibrium 0 20 40 60 80 100 120 140 160 180 0 10 20 30405060 70 80 90 100 wt % furfural temperature c based on data from mains, g.
Cdc niosh pocket guide to chemical hazards furfural. Sampling and analytical methods furfural organic method. Furfuralwater solutiontemperature diagram vaporliquid composition vaporliquid equilibrium physical properties of furfural. Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on ftir instruments or in other chemical environments. Packaging 1 kg in poly bottle 100 g in poly bottle 1, 25 g in glass bottle other notes download our flavors and fragrances catalog to view our entire product line. Physical properties of furfural ifc, supplier in furfural. It is a colorless liquid, although commercial samples are often brown. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at.
Atmospheric removal by wet deposition may be a significant. Please note that we cannot offer bulk quantities for some products. Download our material safety data sheets for furfural. The global furfural derivatives market is anticipated to expand at a significant pace. Opinion of the scientific panel on food additives, flavourings, processing aids and materials in contact with food afc on a request from the commission related to furfural and furfural diethylacetal. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product overexposure signssymptoms ingestion. In a typical semicontinuous sc experiment operating at 180 c and 10 bar, the reactor was loaded with the corresponding amount of catalyst and substrate xylose, glucose or corncob and heated up to 180 c with deionized water 1. An exothermic resinification of almost explosive violence can occur upon contact with strong mineral acids or alkalis. The chemistry and technology of furfural and its many by. Buy high purity furfural analytical standards from chem service inc. Linking to a nonfederal website does not constitute an endorsement by cdc or any of its employees of the sponsors or the information and products presented on the website. Show this safety data sheet to the doctor in attendance.
Furfuraldehyde cas no 98011 material safety data sheet. It forms condensation products with many types of compounds, including phenol, amines and urea. Find 5 hydroxymethylfurfural flavis no and more foodgrade flavor ingredients at. The n 2stripping tests were carried out in a 2 l reactor autoclave engineers, with controlled electricheating and stirred at 500 rpm see scheme 1. Items available from stock in japan will be delivered in 12 weeks. Furfiural yield values have been reported to be 4040% of the theoretical value in closed systems and 5080s when furfural is rapidly removed from the reaction medium. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. Furfural appears as colorless or reddishbrown mobile liquids with a penetrating odor. In this study, the acidcatalyzed conversion of xylose and xylan to furfural by microwaveassisted reaction was.
Furfural is metabolized rapidly and excreted in the urine as furoylglycine, with a smaller portion 0. Furfural is an aldehyde that is furan with the hydrogen at position 2 substituted by a formyl group. Furfural 98011 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Links with this icon indicate that you are leaving the cdc website the centers for disease control and prevention cdc cannot attest to the accuracy of a nonfederal website. Furfural is obtained by the hydrolysis of vegetable matter, such as corn stumps, rice offal, and other materials that contain pentosan. A list of the physicochemical properties of furfural is provided in table 1. Furfural was found to penetrate the skin of rabbits, but with no fatal effect up to 500 mgkg. Furfural is a biomass derivedchemical that can be used to replace petrochemicals. There was a very high recovery more than 90% of dose of radioactivity in all dose groups in 72 hr. Several drops of furfural in standard eye tests with rabbits cause significant irrita. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. This may be a conservative value due to the lack of relevant acute toxicity data for workers exposed to concentrations above 16 ppm. Ac18100, ac18110, ac18125, ac181100250, ac181102500 synonyms furfural. Furfural and its derivatives have several possible applications such as pesticides, solvents for separation of.
Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Furfural yield calculations are simple in batch systems. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. Sds of 5methyl furfural, safety data sheets, cas 620020. Furfural serves as a raw material in the preparation of furan, tetrahydrofuran, and tetrahydrofuryl alcohol and in the manufacture of furan resins, fungicides, and such pharmaceuticals as furacin. Analysis of process parameters during simultaneous furfural stripping. Future feedstock for fuels and chemicals furfural, a sister chemical to the increasingly popular hydroxymethylfurfural or hmf molecule, is regaining attention as a biobased alternative for the production of everything from antacids and fertilizers to plastics and paints. Buy 5chloromethylfurfural cas 1623887, a biofuel precursor used to co process oil crops into biodiesel, from santa cruz. Furfural analytical standards 98011, n121021g chem. This website offers all the customers the much needed information on furfural from the technical data sheets, msds, trading information, to the fullfledged information on everything through blogs. Furfural is a liquid chemical produced from biomass. Due to the polar nature of furfural, it will dissolve quite readily and form solutions with a variety of polar organic solvents like methanol, ethanol, chloroform, and dimethyl sulfoxide dmso.
The fate of furfural 2furancarboxaldehyde was investigated in male and female fischer 344 f344 rats given single oral doses of 1, 10 and 60 mgkg and male and female cd1 mice given 1, 20 and 200 mgkg carbonyl14c furfural. Du pont starts the production of adiponitrile for the manufacture of nylon 6. Furfuryl alcohol sds, msds sheet, suppliers and manufacturers represantative. Furfuryl alcohol, food and flavor ingredient, flavis no. Download msds of furfural us international furan chemicals bv. Product and company identification product name 2furaldehyde cat no. It has an aldehyde group attached to the 2position of furan. Furfural vapor is an irritant of the skin, eyes and respiratory tract. Use explosionproof electricalventilatinglightingequipment. Furfural is available commercially at a purity 98% aldrich chemical co. Iec 61198, mineral insulating oils methods for the determination of 2furfural and related compounds iec 61619, insulating liquids contamination by polychlorinated biphenyls pcbs method of determination by capillary column gas chromatography iec 61620, insulating liquids determination of the dielectric dissipation factor by. The global furfural market demand was 300 kilotons in 20. The revised idlh for furfural is 100 ppm based on acute inhalation toxicity data in humans apol and lucas 1975. Document can be downloaded from legislative information.
1352 680 929 951 1235 882 494 1505 1161 236 914 27 913 246 767 680 1108 1389 253 616 948 630 684 1343 1343 1446 1121 169 42 230